Methods for the Oxidation of Organic Compounds: Alkanes, Alkenes, Alkynes, and Arenes is an account of the different methods used for the controlled oxidation of alkanes, alkenes, alkynes, and arenes. Most of the oxidative techniques considered are illustrated with detailed experimental procedures taken from the literature. This book is comprised of five chapters and begins with a discussion on alkanes, alkyl groups, and hydrocarbon residues. The formation of alkenes, alcohols, hydroperoxides, dialkyl peroxides, cyclic peroxides, ethers, and esters as well as aldehydes, ketones, and carboxylic acids is described, together with the aromatization of cyclic systems. The following chapters are devoted to alkenes, alkynes, and arenes and focus on the formation of compounds ranging from 1,2-diols and oxiranes (1,2-epoxides) to 1,2-dicarbonyl compounds, phenols and their derivatives, and quinones. The formation of dialkynes by oxidative coupling of 1-alkynes is described, along with the oxidative cleavage of arenes and oxidative coupling of phenols. This monograph should be of interest to organic chemists and research students.
This book is comprised of eight chapters and begins with a discussion on the oxidation of alcohols, with particular emphasis on the formation of carbonyl compounds and carboxylic acids.
By definition, BOD represents the amount of oxygen utilized by a mixed population of microorganisms in the aerobic oxidation of organic compounds present in waste water systems at 20°C. The BOD procedure requires dilution of a known ...
SMY mechanism, rearrangement to a final ozonide (97), and/or Baeyer— Villiger oxidation of certain aldehydes and ketones ... 101 The mechanism attracted much attention, and several investigators tried to use it as a synthetic method for ...
Organic Chemistry, Volume 1, 6/E
generated by UV photolysis of O3, oxidized the organic pollutants and allowed the residual O3 dissolved in solution which was later quantified by indigo method to determine COD values.33 The obtained detection limit was 0.81 mg LÀ1COD ...
The major methods of preparing hydroperoxides may be divided into two groups: oxidation with oxygen and reactions with ... the product hydroperoxide, other organic peroxides, heavy metal salts such as the “metal dryers,” ultraviolet ...
When conditions are quasistationary, v i 1⁄42kt[RO2.]2, chains are long (kp[RH][RO2 .] ) vi), and the rate of chain oxidation is the following: v 1⁄4 k p (2kt)À1=2[RH]v1=2i (2:1) The values of the kp(2kt)À1/2 parameters for the ...
The most common methods of wet digestion employ sulfuric acid or mixtures of sulfuric acid ... While it accelerates the destruction of organic matter, it is only effective in a low range of oxidation potential, and the sulfuric acid is ...
The Handbook of Organopalladium Chemistry for Organic Synthesis is the first comprehensive and authoritative handbook on organopalladium reagents and catalysts.
4.24 (A) j(E) polarization curves obtained during the electrooxidation of a preadsorbed saturated layer of CO using ... Review of different methods for developing nanoelectrocatalysts for the oxidation of organic compounds, Electrochim.