Higher Excited States of Polyatomic Molecules, Volume I focuses on the spectra in the vacuum-ultraviolet region between 50,000 and 100,000 cm-1. This book explores the higher excitations in molecules beyond 50,000 cm-1. Organized into three chapters, this volume starts with an overview of the excited-state properties of a molecule and the excited-state ionization potential. This book then proceeds with a discussion of the original classification of the properties as well as the types of excitations observed in the vacuum-ultraviolet. Other chapters discuss photoelectron spectroscopy, which is an independent, self-sustaining branch of molecular spectroscopy. This text examines as well the distinction between valence shell and Rydberg excitations. The final chapter deals with several topics, including the saturated molecules that are classified as having all valence electrons, the alkene absorption spectra, and the spectroscopic data on boron compounds. Analytical chemists, photochemists, molecular spectroscopists, and researchers will find this book extremely useful.
For a long time, the Kasha rule (Kasha, 1950), regarding the absence of fluorescence from higher excited states of polyatomic molecules, was considered as absolutely valid with the only exception of azulene (Beer and Longuet-Higgins, ...
Concluding Remarks In conclusion, we now begin to understand the lowest excited singlet and triplet states of olefinic and polyenic systems. As discussed above, a large diversity of ... Higher excited states of polyatomic molecules.
Low and High Rydberg States C. Sándorfy ... They fly to the detector as neutral Rydberg excited hydrogen atoms and are then ionized by the field of the detector. ... (4) ROBIN, M. B. (1974) Higher Excited States of Polyatomic Molecules.
Frontiers and Advances in Molecular Spectroscopy once again brings together the most eminent scientists from around the world to describe their work at the cutting-edge of molecular spectroscopy.
15. M. B. Robin , Higher Excited States of Polyatomic Molecules , Vol . 3 , ( Academic Press , New York , 1985 ) . 16. W. T. Borden , Modern Molecular Orbital Theory for Organic Chemists , ( Prentice Hall , Englewood Cliffs , New Jersey ...
A. Amirav, U. Even, and J. Jortner, Excited-state dynamics of the isolated ultracold ovaleneu molecule, J. Chem. ... Luminescence from higher excited states and vibrational relaxation of polyatomic molecules in solutions, Opt. Spectrosc ...
Contents:Two-Color Double Resonance Spectroscopy For the Study of High Excited States of Molecules (M Ito & M Fujii)Resonantly Enhanced Multiphoton Ionization — Photoelectron Spectroscopy as a Probe of Molecular Photophysics and ...
Figure 1.3 Simple model of the process of photodissociation of a polyatomic molecule by an intense IR field: stage ... stage II—high excitation (vibrational heating) of molecules upon transitions between highly excited states; ...
n 1,1-diphenylethylene 9.0 60 cis-1,2-diethoxyethylene 0.36 13o 41o 2.3k,p ethyl vinyl ether 0.014 0.20 k,m ... 4.0ee 28gg 0.50c triphenylamine 6.6 7.6hh 0.31c N,N-diphenylamine 13 130 c Aromatics ii 17 benzene 0.028 jj 0.0001jj toluene ...
R. A. Kennedy and C. A. Mayhew, Int. J. Mass Spectrom. 206, i (2001). Y. Liu, C. A. Mayhew, and R. Peverall, Int. J. Mass Spectrom, and Ion processes 152, 225 (1996). G. K. Jarvis, C. A. Mayhew, L. Singleton, and S. M. Spyrou, ...