The Role of Rydberg States in Spectroscopy and Photochemistry: Low and High Rydberg States
- ISBN-10
- 0792355334
- ISBN-13
- 9780792355335
- Category
- Science
- Pages
- 524
- Language
- English
- Published
- 1999-01-31
- Publisher
- Springer Science & Business Media
- Author
- C. Sándorfy
Description
The aim of this volume is to offer a balanced overview of molecular Rydberg spectroscopy as it has developed over recent decades. Recent evolution has split Rydberg spectroscopy into two apparently distinct fields: the one concerns the low (n=3-5) Rydberg states, the other the very high (typically EMn/EM”150) Rydberg states. The former is aimed at spectral levels where Rydberg, valence-shell, and intermediate-type states interact, with a variety of photochemical consequences. The latter considers states extremely close to the ionization limit, from whereionization is possible with a very slight amount of additional energy. Recently developed techniques make it possible to produce ions in well-defined electronic, vibrational and rotational states, including states resulting from spin-orbit or Jahn-Teller splitting. It is then possible to study the structure and reactions of such state-selected ions as well as those of the corresponding neutral molecules. These techniques amount to badly needed high resolution photoelectron spectroscopy.
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Other editions
-
- 2006-04-11
- 512 pages
- Ebook
- Springer Science & Business Media
-
- 2002-07-31
- 540 pages
- Paperback
- Springer Science & Business Media
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